I think I need to return that I get something completely different, such as foil covered PIR plus plasterboard.
If that's significantly cheaper than the laminated board, and it often is, then yes. Check what seconds&co have.
But then I still have the issue of fixing it to the wall - I guess I can glue just to get it in place, and then mechanically fix when everything is where I want it to be?
Yes, I'd probably glue the insulation to the wall and then glue the plasterboard to the insulation, and put a few mechanical fixings through everything to make it fire-secure.
I'm honestly not sure about glue on foil-backed boards. The only similar thing I've done was celotex pl4000 onto brick using sticky-foam. The back of pl4000 is not "foil colour"; it's cream IIRC, but I think it actually is aluminium (and hence moisture-proof) but with a layer of cream paint or similar. Anyway it sticks fine with sticky-foam, and the celotex website says suitable for dot&dab. I'm not sure about the boards that acually look like aluminium foil.