I assume it means what it says - that the minimum current is 100mA in a 20V circuit (i.e. 20V across contacts when open).I don't really know what "100mA(20V)" means.
No - at least, not if the issue in question that that discussed in the link you posted. That problem (of poor electrical contact between contacts, due to surface oxidation etc.) occurs only with small currents in low voltage circuits. Although I don't fully understand it, it is said that higher voltage circuits apparently tend to 'burn off' the oxide coating on the contacts which causes the problem. The minimum current will therefore vary with voltage, and as I said, they have only told us the minimum current at one voltage. I would imagine that at 230V there is probably no (or no significant) 'minimum'.Surely Minimum Switching Current is either that (at all voltages) or variable.
As I said, I personally have rarely seen a 'minimum switching current' specified for either switches or relays.Other products are similarly specified and some don't mention MSC.
Kind Regards, John