Exactly.The bathroom rad gets hot when only ch is on also but if there is a path from to the rest of the system I guess that would happen also.
Solve one problem and you have solved the other.Regarding the subject, getting ch when hw is on is what needs sorting but I'm pretty sure this flow issue is heating the hw when only ch is on therefore making the cylinder stat and mv irrelevant.
Also in the middle pic of the left side of the boiler there are two 22mm pipes entering the boiler. The rads and cylinder seem to return to the bottom one. The flow comes out of the right side.
What's the top left pipe?
But you said it came out of the boiler on the left top - as in your pic.It's the one between the HW MV and the cylinder vent that runs behind the centre of the cylinder and up the top on the right. I've labelled it "15mm?"
I've added it to your drawing.The 22mm one that I wasn't sure about in the photo isn't in the drawing but it does come out of the top left of the boiler and head straight up into the ceiling with nothing else connecting to it. As the other two 22mm pipes going up seem to to be CHF and CHR it must be the vent? There is a 22mm pipe with a U bend over the feeder tank in the loft.
As you say - weird.I've done the test on a couple of radiators downstairs.
With HW only left valve heats up first
With CH only left valve heats up first.
Weird because I thought the return from the bathroom rad may have been heating up the other rads but if that was the case then wouldn't it be the right valve that heats up.
The left side of the CH MV definitely stays cold when HW only is on.
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