other wiring centre, the white one.
7 connected to 5 in other wiring centre, I.e. pump.
Yet there appear to be two wires in 7, I assume that the black wire is the one that goes to 5 in the other wiring centre (ie the pump) but there is another brown/red wire that looks like a link to 5, which you say also goes to the pump. Is that correct? After reading the description of the other wiring centre terminal 5 I think it is but it just seems strange someone has added a link to duplicate wiring already in place.
I think @ericmark is on the right lines, with fully pumped systems all motorised valves will start both the pump and boiler, in your case the heating should start the pump and boiler, but the hot water only the boiler. So some isolation is needed between the pump and boiler, i.e. they can't be connected together as it would be impossible to have one on without the other.
EDIT
Also, the black (messy) wiring centre you describe as having 8 terminals; the photo shows 9. Looking at it, there seem to be two vacant terminals which would be 6 & 7 in the photo, you only mention 6 being vacant, so I suspect what you describe as 7 and 8 are really 8 and 9.
If above assumptions are correct, I reckon:
1. Hive 1 is set up as gravity HW pumped CH and is controlling the boiler accordingly. The only connection to the boiler is terminal 2 of the messy wiring centre that is powered by the HW on from Hive 1 and nowhere else.
2. Hive 2 is wired to the downstairs motorised valve and its orange wire energises the pump via messy wiring centre 5. It has no connection to the boiler. So, unless the Hot water is on at Hive 1 to start the boiler the downstairs heating won't work.
If the orange wire from the downstairs motorised valve was wired to a relay with two contacts instead, then one contact wired to the boiler and one to the pump that would allow the downstairs heating to control the boiler and the pump, with the relay providing the required isolation between the two items.
I also have some concerns:
1. The hot water cylinder thermostat will close the HW motorised valve when the hot water cylinder is hot, but the boiler will stay on while ever the Hive 1 HW remains on. So unless the heating is operating there is nowhere for the water to circulate. I'm a sparky not a boiler expert so that maybe ok with your type of boiler.
2. The orientation of the pump. Usually they have bearings that are water lubricated and should be mounted with the shaft in certain axes (i.e. horizontal). Yours isn't. It appears to be mounted with the shaft vertical like the one on the bottom left below, with a red X though it.
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