Just to update, as recommended on this thread, put 2 litres of X400 in the system today (19 radiators in house) put this in via the magnetic filter which I understand is an acceptable way of doing this. Will leave this in until the new year and see what happens, but assume I will need to replace the junction. I wont lie there is a temptation there to clear out the blockage by removing the pump and give it a poke, but concerned that I will dislodge a large chunk of magnetite that will cause bigger problems somewhere else! Thanks all again