As I said before son had same problem, and all down to lock shield valves not being set.
If boilers had a gauge built in showing output it would be easy, but in the main they don't, you know it is running, but not a clue if 10 kW or 30 kW output or anywhere between.
My boiler (oil) is easy, it has a fixed output, so if running it is producing 20 kW if not 0 kW and so I have a good idea how hard it is working by the sound it makes when running.
Your boiler (gas) has a variable output, so it may be running but no idea if 10 kW or 30 kW or anywhere in between, so you need to ensure the water is cooled by the radiators to a point where the boiler is giving full output when the home is cold. So you want the water to cool in each radiator around 15°C between input and output of the radiator, maybe more.
I am an electrician not a heating engineer, so I don't have his array of tools, and I will admit to measure the incoming pipe temperature and outgoing pipe temperature is not easy without a differential thermometer. I tried a aim and read thermometer and the reading varied too much.
So I closed each lock shield valve starting closest to boiler waited for feed and return pipes to go cold then opened lock shield ¼ turn at a time with some time between each adjustment, until one pipe got just a little warm, then moved to next radiator, this is far from perfect, but a good start.
TRV heads take time to open and close, mine exercise to stop TRV's sticking mid day every Saturday and it takes around 4 minutes to open/close and return to setting, if the flow in the radiator is too high, radiator can get stinking hot before the TRV can adjust flow. But I have four Energenie MiHome TRV heads which report to the PC target and current temperature, so by moving the heads radiator to radiator I can monitor performance and fine adjust the lock shield valve.
The process is simple, target under current assuming target has not just dropped, close lock shield a tad, the reverse not quite so simple as target over current may just need more time, but if regular then open a tad. Once the lock shield is set even with a mechanical wax TRV head the rooms do keep to temperature set.
In mothers house with gas modulating boiler before setting living room radiator tended to be stinking hot or cold, after setting it seemed to stay warm all the time but not stinking hot, this resulted in when sun came through bay windows the room still went up in temperature, but radiator cooled quicker, so maximum temperature when set to 20°C did hit 32°C in the sun, but after setting 24°C maximum, rooms where sun did not cause a temperature raise were within 1°C of the setting, it really did work well.
Only down side was the Energenie Mihome TRV heads have a rather OTT anti-hysteresis software built in, so would set to 22°C at 7 am and 20°C at 8 am to get room warm quicker. Makes like the Drayton Wiser claim to have built in algorithms to counter this problem and work out how long it takes to heat the room.
In theory the installer should set the lock shield valves before he leaves, part of the commissioning, but with parents house although the firm specialised in fitting central heating, they seemed to use cheap labour and a few proper engineers and so many errors made, including the system never being commissioned.
Every lock shield valve had been left wide open.