This is a guess, I will guess the lock shield valves are not set correctly and as a result the the boiler is modulating. The modern gas boiler has a variable output. It seems
reading the manual your boiler has an output 10 kW to 30 kW, to get the 30 kW the return water must be cool.
I am electrician so not sure on valves, but I thing around 15°C temperature drop across the radiators, unless set you get room by room heating, so easiest room to heat the radiator gets hot, and then the TRV starts to close, as it closes it heats next radiator, and so on.
The mistake every one makes is to look at the cold radiators, where the error is more likely to be with the hot radiators. So most likely you need to turn down the lock shield valves on the hot radiators.
I now have a thermometer I could use, just aim it at in and out pipes, but before I had that tool I would turn off the Lock Shield closest to boiler, then 1/4 turn at a time back on until one pipe gets just warm, and then repeat with rest, once all done they may need further tweaking, but it should be a good start.
The other method if not due to poor lock shield settings is to use programmable TRV heads and actually design the system to heat room by room, but I suspect the lock shield valve setting is the fault.