My towel rail is thermo syphon, and even if pumped, too far from boiler to act as a by-pass.
Basic idea is as the TRV's close, the by-pass opens allowing hot water back to boiler, which in turn reduces output of boiler, first my modulation if that type of boiler, then the mark/space ratio, some boilers have anti-cycle software which increases off time if water returns hot after boiler auto restarts, all this is by-passed if a wall thermostat switches it off, aim is to have anaguloge control when ever possible, so TRV rather than on/off thermostat.
But closer the by-pass is to boiler the better, the idea of one radiator without a TRV was before we used by-pass valves and modulating boilers. Fitting a TRV on mothers hall radiator was the biggest improvement of everything I did to her central heating.
However the two thermostats wall and TRV needs to either be carefully matched, or linked, and I found the TRV is always a lower temp to wall, so not the same temp set, I found TRV around 2 degs C lower to wall thermostat.
I was slow to fit a TRV to hall radiator as it seems I was reading outdated books which said don't fit TRV in room with thermostat, but when I considered it, in the hall the TRV makes sense, as it allows a quick recovery after front door opened, but then slows down before turning boiler off prematurely so rest of house gets cold.
However does not work too well with this house, as hall cools too slowly, the lock shield can adjust heat up speed, but not cool down speed.