at STP water cannot exist above boiling point, it turns to steam.
yes it can..
if you microwave a cup of distilled water you can super heat it to more than 100°C and it doesn't boil...... until you drop a sugar cube or spoon etc into it.
they did it on mythbusters...
Not tried that (would not want to at home) but how do you know it is over 100 C? The implication is that inserting a thermometer would cause it to boil. Do you believe everything you see on TV?
To me a superheated fluid means it has been heated above its "natural" state by increasing the pressure, release the pressure and it gets interesting. BTW steam is a fluid as is water, steam is invisible, water vaopur can be seen (and no, water vapour is not steam, it is small droplets of water in the air, steam is evaporated water.) vapuoinstantaneous boiling.
Superheated liquids are VERY DANGEROUS