What you say makes perfect sense, something making the case live, but why isn’t this being discharged to earth, is the other quandary. Could the mcb be faulty?
Maybe now is the time to just get a new rcb board and get the whole house earths checked.
Your more immediate problem is to identify as a matter of absolute priority, what is actually live. You can do that, as suggested above, by connecting meter in turn between each appliances metalwork and a known and reliable ground. If necessary, extend the lead to ground, with an extra length of wire.
Once you have identified the live item, then turn it off via the MCB if the oven, or unplug the toaster.
If the toaster, then you need to ensure the earth pin at the socket is not live and if it is you would need to isolate the kitchen ring.