The boundary line is the centre of your party wall. Whether that is the same as the chimney, you will need to checkDo you reckon that the centre-point of the chimney would satisfactorily indicate the boundary line?
Your photo and the plan image show your extension wall and chimney in different places
If, going by that photo, your extension is on the boundary, then your eaves and gutter are overhanging the boundary, so you may want to keep quite about boundaries