I know there are risks with radweld, but I really didn't use very much of it. Less than half of the bottle over a period 2 to 3 weeks. I still have some of it. But I guess with the second leak(the one in the hose) maybe the radweld remained in the cooling system while the water and coolant emptied and then perhaps it blocked up something? It's probably unlikely as Halfords would probably recommend using a full bottle of radweld to fix the leak that I had, and as far as I know it needs air and heat to seal over holes, but it allegedly only seals holes which have air coming through from the outside? I'm also wondering if radweld did block something, for example preventing the pump from working, would that not prevent anything passing between the reservoir and radiator and/or back again. Because fluid does seem to be passing between the two, albeit abnormally.
EDIT: as of now, I'm fairly confident that there is no oil in the coolant expansion tank/reservoir. However, there was coolant and water trying to overflow out of that tank yesterday when I first noticed the thermostat rising.