There's a diagram in your manual which indicates exactly what all of the pipes are. Post a picture of it if you have any questions.
Better that than someone on the internet inadvertently advises you to cut into your gas pipe.
Your heating return is the 22mm pipe at far right side of boiler, (the last one before the 15mm pressure relief pipe which is in 15mm copper) the pic shows it coming from boiler and coming out and running vertically up right side of boiler casing.
The one that runs horizontallly that you put red mark on is the heating flow.
I'd be tempted to get a pipe slice on that short 22mm stretch that comes out of the back of the boiler and then join a new elbow to it.
You may find it easier to remove the return pipe completely from the boiler, then you can solder your new "U-bend" away from the boiler where you're not so tight for space.
I actually meant cut the horizontal piece that comes out of the boiler, but I guess you could cut there too.
Search for "solder mat", Rothenberger do some decent ones.
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