try turning the boiler stat down a bit and see what happens - if set too high or to max they sometimes cause the boiler to overheat
The boiler should be able to work fine with the stat on maximum, it's designed to. If it doesn't then the system is at fault.
some boilers overheat when on maximum, the potterton profile is a common cause of this - I know it;s designed to but it just doesn't - like isolation valves under the boiler are designed to be used to change a part without draining down whole system etc - but we know these are not always straightforward too!