I get 288l now, which is a lot of water! Did I divide by 4 twice in my head? Oh well, so much for that.
Good, so the typical 70 litre capacity system will reach 70 C in about 15 minutes if it starts at 20 C so in 15-20 min it will have nearly reached the set 75 degrees.
Of course there is the heat loss which is somewhat proportional to the temperature difference between rad and room. That will only begin to be significant as it starts to get to about 50 C as below that there will be little temperature difference and little thermal convection currents which increase the heat output.
Back to the OP. If you are using significant hot water late at night and shortly before heating is timed off then increase the morning reheat to about 40-50 minutes as at 1700 30 minutes was not enough.
You need to have the hot water fully hot by the time the CH is required. Then have the hot water OFF for the first hour of the CH to enable the system to heat up. The HW can be timed to be back on after that hour because by then the house should be warm.
The boiler cycling will be a feature of an over powered boiler with a minimum power output of perhaps 10 kW so it will cycle a lot. Its important in your situation to set ip up in the best way. Can you time the on and off cycles on CH only, once its hot, so that we have an idea. Time it over about three cycles to get a better average.
Tony