If you have only one rad turned on, the boiler will need to cycle as it can only modulate down to 6kw. This makes fault finding difficult. Remove all TRVs(*) and open any wheel valves (not lockshields). Set the display to show nF/0 (it will go back to just dots after a short time) then turn on CH. It's now a case of monitoring t1, t2, and nF (lots of button pressing) Keep a note of the readings. You may have to do this for some minutes until a pattern appears, e.g boiler cycling on/off every few minutes. Post the info.
Have you set the display (P6) to 1? Doing this will give useful info on the boiler status.
Do you have hard or soft water?
I am wondering if the diverter valve has got seized up, partly open, due to a build up of limescale. If so, the water would be circulating all the time through the DHW plate heat exchanger as well as through the rads. The hex will be the easier path, so more water will flow that way. This would account for the very high DHW temperature and the rads not heating up.
(*) TRVs can sometimes be stuck shut, even though the pin is up. This is because the pin is not attached to the part which shuts off the flow (think of an upside down mushroom with stalk separated from head.) You can often free these TRVs by tapping the valve body with a hammer.
Have you set the display (P6) to 1? Doing this will give useful info on the boiler status.
Do you have hard or soft water?
I am wondering if the diverter valve has got seized up, partly open, due to a build up of limescale. If so, the water would be circulating all the time through the DHW plate heat exchanger as well as through the rads. The hex will be the easier path, so more water will flow that way. This would account for the very high DHW temperature and the rads not heating up.
(*) TRVs can sometimes be stuck shut, even though the pin is up. This is because the pin is not attached to the part which shuts off the flow (think of an upside down mushroom with stalk separated from head.) You can often free these TRVs by tapping the valve body with a hammer.