The temp at the boiler is Flow 70.2, return 42.8. Don't know how to sort this temperature difference.
The wide difference means the water is flowing too slowly round the system. This will be due to either the pump set too low or high resistance in the system, including a blockage somewhere.
It's easy to check the pump speed. Remove the boiler outer cover and you will see the pump in the bottom right hand corner. It's a big round device. There will be a rotary switch on the square box part of the pump. This should be set to the highest number. If it is already set to the highest number, the problem must be due to high resistance/blockage in the system.
would the only reason for the return being slow on the dining room rad be a blockage at the return pipe? If it is, could this mean that this will be the reason that the rad may not be fully heating up?
If it was just the one rad which had a wide differential. I would agree that there was a blockage in that rad circuit. But the differential at the boiler is also much wider than it should be, which points to a system wide problem.
The next thing you need to do is check that the pump is set to max speed.
Incidentally, do you get any of the warning lights, A and B, coming on? If so which? The user manual explains what they mean, but if you have no manual, here's the info (A is red, B is yellow):
Neon
B Flashing very slowly (every 5 seconds) -
Electricity supply to the boiler is on.
B Illuminated continuously -
Burner is alight.
B Flashing on and off -
Temperature sensor fault, contact your Service Engineer.
A Flashing on and off -
Overheat thermostat has operated. Rotate selector switch to the reset position (3) to reset. If this continues to happen, contact your Service Engineer.
A Illuminated continuously -
Burner has failed to light. Rotate selector switch to the reset position (3) and the ignition sequence will restart after a delay of about 30 seconds.
A and B Flashing on and off at the same time -
Blocked flue or fan fault, contact your Service Engineer.
A and B Flashing on and off alternatively -
System pressure is very low and re-pressurisation is required.
A Illuminated continuously and
B flashing -
Pump fault or restricted flow.
The first two are normal, the rest indicate a problem somewhere. The last one is probably the most important in your situation.