The whole problem I found was the software which came with the valves has no instructions as to what it does, in my case using MiHome eTRV's and I found if set to go from 16°C to 20°C at 6 am by 8 am when I wanted 20°C it had not reached it, I had to set it to go to 24°C at 6 am then at 8 am back down to 20°C to get the temperature required.
Same going down, from 22°C at 9 pm had to set to 16°C even though I wanted 18°C for the valve to close enough, seemed I had to do this at every change, and it would also change due to sun light through bay windows, and the software built into the valves was too slow to react to keep the room from over heating, I was very disappointed, they worked, can't say they didn't, but not as wanted.
The biggest help to controlling the house, was not the eTRV but actually fitting a simple TRV on radiator where the wall thermostat was fitted, what it allowed was fast heating of hall when front door had been opened, but then slowed down the heating after 18°C so enough time for rest of house to heat up, before the wall thermostat switched off boiler at 19°C. Clearly not a problem with EvoHome as you don't need a wall thermostat, but had I done that to start with, the eTRV would not have been required.
My eTRV has the ITTT system, but found near impossible to write my own software, it would require reverse engineering to work out how to write it, so in real terms only option is to select an app already written from the MiHome web site.
So in theory you should be able to write a program so if the target is above the current on any eTRV then switch a relay on so powering up boiler, the relays are made and sold, so hardware wise it can be done, however software wise I could not find the ready made software to do this, or enough info to allow one to write ones own software app.
I can't even find out where each bit of the program is stored, we have the valve head, the hub, and the internet connected server, one would hope if set to change from 16°C to 22°C at 6 am that would be in the valve, but one does not know if this is the case or not, the web page has last seen at moment says 1 minute ago, but I have looked some times to set 2 days, as in the summer when that was reported don't know what the valve would have done. However if I was doing it again, I would not use WiFi connected eTRV's I would use local set type, these would work just as well for me, as although it tells me temperature of room, I have no way of using the info.