TN-C-S and PME is the same thing..
Even though I imagine (hope!) that you wouldn't find a TN-C-S supply that didn't also have PME, they certaintly aren't the same thing, and theoretically don't have to come together.
TN-C-S means literally what it says - the Neutral and Earth start off (at DNO end) combined ("-C" - i.e. there is just a 'neutral' conductor) and then at some point, usually on entry to a building, separate ("-S") into separate neutral and earth conductors. Anything that fulfills that definition is TN-C-S, and still would even if it didn't have PME.
'PME'is a totally different issue and, again,simply means what it says - multiple earth connections (to the 'combined' neutral conductor.
As far as I am aware, the only 'advantage' of TN-C-S is that it saves the DNOs some money, but to make it a bit less dangerous in the event that a break occurs in the neutral supply cable, they install PME, such that there are frequent connections between their neutral and earth.
As has also been observed, I presume there is no theoretical reason why PME cannot be applied to TN-S systems, but I don't know if this is ever actually done.
Of course, thanks to Main Protective Bonding and metal service supply pipes, both TN-C-S and TN-S would tend to aquire 'PME' via customers' premises, even if the DNO didn't provide it!
Kind Regards, John.