You said you believe they did this originally. if so then the original measured air end pressure of 2.8bar would only result in a final pressure of 4.62bar even if 250L was heated to 60C, the air end pressure could be as low as 1.2bar before the expansion valve would be approaching its lift pressure of 6.0bar again even if heating 250L to 60C, you said the EV was lifting before recharging which it couldn't if the EV was checked as suggested (2.8bar) above so difficult to have any confidence. You should certainly get a discount for labour, I would also suggest that the connecting pipe between the EV and the cold supply to the HW cylinder is removed and proven clear. Also your engineer should check the new EV pressure before mounting it as a small percentage of these have come with no charge and are "flat".I assume depressurizing it by turning the stop valve off just below the combo valve...then opening the hot taps to take the pressure off. I believe they did that, and then check the pressure on the EV...topping up appropriately. They did not disconnect the EV physically if thats what you meaning. They did check the pressure of the EV after depressurized, and topped up.
Hopefully not a problem but I would also check out (or get it checked out) the static cold water pressure at a outside tap.