Thats got to be a wind up surely?
The cause of your problems are:
1. Bad installation, dirt in the system, inadequate flushing and/or lack of correct inhibitor. 80% of F.75s are related to carp in the boiler as are leaking DV spindles. There are other issues, but lack of correct servicing and dirty systems are top of the small list. I bet the DV isn't leaking clean water right???
2. Incorrectly diagnosed problems by visiting engineers.
If you had these problems within the 2 year warranty, then a call to Vaillant would have seen you with the upgrade kit fitted and advise on the water quality (if needed).
Possibly the DV is partially seized and staying in the Heating position and causing the rads to warm when the boiler is doing warmstart (pre-heat). Turn off the warmstart to confirm this. If and when the boiler 'stays on' press the i button instead of turning it on and off. There is no case that the heating would be on or the pump running and S.0 or S.30 are displayed.
Not a "wind up" as you put it, at all. First, the warranty was for one year, not two. Second, the installers came out around a dozen times in that first year to try and fix, or in the case of the leaking hoses fix, the boiler during the warranty period, then said they had to charge for the call outs over the following year (perhaps another dozen or so). As it was clear that the installers couldn't resolve the problem, I had another firm out to look at it, but they were every bit as stumped.
I've had several assurances that dirt in the system isn't the cause. The original installers flushed the system for a couple of hours or so, using a large tank on the floor with filters and a magnetic trap, before they installed the boiler. They also installed a filter on the return pipe just under the boiler, made by a firm called Magnaclean. The last repair to the boiler was the replacement of the diverter valve last year, and when this was replaced the engineer commented that the boiler was clean inside and that he didn't believe that the long-standing F.75 problem was caused by dirt. The boiler has been serviced each year, and kept topped up with inhibitor.
The diverter valve did develop a leak around the shaft, dripping what looked like clean, but rather smelly, water on to the worksurface under the boiler. I have the old one (the engineer left it behind when he replaced it) and it looks clean inside and was still working when it was replace, it just leaked. As far as I can tell the new diverter valve is working properly, as even when the boiler gets stuck with the heating on (with no demand from the room 'stat/programmer) it still switches over from heating to hot water mode as normal.
According to the diagnostic display, there is no call for heat (it shows either S.0 or S.30 when it's not in anti-cycling mode or pump over-run mode) yet the boiler will still run in heating mode with normal burner and temperature control as far as I can tell, unless I turn the temperature dial to zero to shut it off, or go through the ritual of turning off the power, waiting, and then turning it back on. Even with the programmer/'stat disconnected the boiler continues to run as if it were being called, which to me seems to indicate an internal fault condition of some sort.
[edited to add:] Sorry, I just noticed your mention of an "upgrade kit". Is this the replacement of the pressure sensor and pump? If so, then that was done under warranty, I believe at the direction of Vaillant.