I keep noticing the "silicon" being implied as important in aluminium - silicon heat exchangers. Some folk seem to think this is new technology - it isn't. I've read that the heat exchangers are "coated" with silicon, which appears to be completely untrue.
Silicon is added to aluminum castings to make them harder and cast better - the flow is better at lower temperatures. Some other physical properties are improved too, eg the thermal expansion is reduced, but I don't think those are significant.
I haven't found much about the effect of Si on corrosion resistance in Al castings. Basically it isn't added to affect that, and I wouldn't be surprised if it makes Al slightly more prone to corrosion by some chemicals. Silicon doesn't form any sort of oxide on the surface of aluminium either. (As for example chromium does on stainless steel). Thinking of condensate, mild acids generally, don't attack aluminium; its oxide protection is highly protective.
So unless someone can enlighten, there appeas to be no "silicon" issue.
I daresay we're going to see dramatic pictures of Al alloy heat exchangers turned to grey mush, and the alloy blamed. It IS a reactive metal. If you fix a sheet of aluminium, outside, with brass screws, the aluminium may have all gone from around the screws in a year or two. That's an electrolytic effect, of course, and one to be worried about.
The worst thing you could do would be to use a lot of aggressive flux, which would introduce chlorides, and then not flush, then not use an inhibitor. (This would also apply to stainless steels - to which chlorides are very aggressive). Strong alkalis will also kipper Al alloys quickly.
Porous castings, parts with high or cyclic stresses, or sublect to erosion by particulates in high flow areas, could all present problems.
Al/Si alloys have been around long enough, surely, for responsible manufacturers to NOT have problems, as long as responsible installers do their bit. But I don't think comment is needed on the responsibility of manufacturers or installers.
Has anyone actually seen much evidence of short life for Al alloy heat exchangers? I haven't, yet, but these remain weak, reactive alloys, which won't be as forgiving as some of the materials we're used to.