Have you tried opening the HW motorised valve, closing the CH valve, and running the pump? That would put pumped flow through the cylinder and might clear any airlock.
Also the way your kit is piped, with some wiring mods it could be converted to a fully-pumped S-plan system, giving improved HW performance.
I wouldn't be too sure the pump isn't at fault. Some years ago I had a slight kettling noise, but had no reason to suspect the pump. Then the pump started to vibrate badly so I changed it. That cured the noise, and was OK at speed 1, vs speed 3 on the old one. When I looked into the old pump the impeller was full of sludge. Consists of 2 stainless steel discs 2mm apart and the gap was solid with sludge. If yours is like that, you could give it a good clean, no need to buy a new pump. And no need to disturb the pipework, just remove the motor/impeller, 4 Allen bolts usually.