Well, after the comments on here, I've cancelled the engineer coming back tomorrow with a new PCB. I now need to find another who can come out in a hurry and has GlowWorm knowledge.
To answer some other comments, the flow sensor was disconnected, as were all of the other low-voltage elements, one by one. Also, some internal reset stat something or other was checked too if that makes any sense.
And frustrating isn't the word - infuriating is closer to it. Just don't see the point in a forum where people can only answer with "I know what's wrong but can't tell you" - just needs a nah nah na nah nah and a sticky out tongue to go with it
I understand the logic about gas safety, however I imagine the chancers are going to meddle regardless, whether you share info on here or not. I doubt you are protecting anybody and in reality just making it difficult for people like me, who could have shared the info with my engineer and had a fixed boiler and an engineer who has gained some more knowledge for the future - everyone benefits. Anyway, I sense I'm getting into an argument I won't win on here so will say no more.
Options for tomorrow are either contact GlowWorm themselves and look into the fixed price repair and service contract (is it any good?) or find a local GlowWorm specialist who can come out. Decision may come down to whoever can turn up first. And if I take another punt on another random engineer, who's to say they will know any more than the last?!