I think it just means that ter 7 is just linked to ter 1, the switched live, and yes 2 to 10 if they read 240v are fine.
The MPV should certainly move right over to CH only (port A open) when CH only is selected and not apparently be in the mid position feeding both CH and HW., this could be a programmer fault (as suggested above) because the HW OFF contacts actually power the valve to the CH position. The other strange reading is the HW only test which you might do again some time, shows this N to 7 voltages of 6V to 180V yet N to 1 is perfect, also the boiler runs perfectly.
What you might do, CH & HW both on but turn the cylinder stat right down and see if the valve now moves to the CH position only, with no HW cylinder heating, this would point to the HW OFF contacts faulty or maybe never connected?, however any of this still shouldn't IMO cause the boiler to hunt since all reading of N to 1 (the switched live at the boiler) show a steady 240V so don't know where the answer is, lets see what you get with this test above.
HW only
2(N) - 1 240v constant
2(N) - 4 all over the place
2(N) - 7 random figures as low as 6v and up to 180v
I don't have a room stat just TRV on rads.
The MPV should certainly move right over to CH only (port A open) when CH only is selected and not apparently be in the mid position feeding both CH and HW., this could be a programmer fault (as suggested above) because the HW OFF contacts actually power the valve to the CH position. The other strange reading is the HW only test which you might do again some time, shows this N to 7 voltages of 6V to 180V yet N to 1 is perfect, also the boiler runs perfectly.
What you might do, CH & HW both on but turn the cylinder stat right down and see if the valve now moves to the CH position only, with no HW cylinder heating, this would point to the HW OFF contacts faulty or maybe never connected?, however any of this still shouldn't IMO cause the boiler to hunt since all reading of N to 1 (the switched live at the boiler) show a steady 240V so don't know where the answer is, lets see what you get with this test above.
HW only
2(N) - 1 240v constant
2(N) - 4 all over the place
2(N) - 7 random figures as low as 6v and up to 180v
I don't have a room stat just TRV on rads.