The starting point for any oil burner setting is matching the manufacturer's settings for nozzle and oil pressure. These are the constants of fuel for the required output for the boiler. The air setting can never be stipulated as it varies with flue conditions. You have raised, inadvertantly, another option to your problems. What photocell do you have fitted? The Sterling burner usually comes with an FZ 80mm photocell, but for some reason, Worcester only ever used the shorter one as used on B9 and B11 burners. With the short photocell, any hint of overairing tending towards 'blue flame' combustion, will make the flame difficult to 'see' with the short photocell. This may be why the burner ran under supervision of a lamp light, but not in the burner, although you could see a flame it may not be of the correct intensity.