Therein lies the problem
There is nothing complicated about the system
In essence, sure other pros will correct me on this if I am wrong, heated water flows into a large bore pipe and return to base of the boiler exchanger. To set up circulation, a pump is used that moves the water in the ring and through the boiler.
The radiators are plumbed with 3/4" or similar size pipes with flow entering (usually ) at the top and opposite bottom is where the primary water leaves the radiator to join the circulating stream of water. Flow in the radiator will be a mix of gravity and use of swept tee (if the installer had swept tees
While the loop is pumped, the primaries going to the cylinder are not. I would remove the zone valve and fit a pump there. I am quite confident there is no restriction or whatever- it is the 22mm and 15mm as well as the high resistance coil, not forgetting the flow pipe rising then dropping down to the cylinder that is stopping the circulation due to high circuit resistance.
I would fit a pump to that loop, switching carried out by the cylinder thermostat. It would not hurt to look at smart radiator thermostats to keep gas usage in check enabling a solid uneconomical boiler that does not require expensive re[airs to be put to good use. Will enable summer/ winter setting on the programmer.
If possible to take cylinder pipes to the boiler, two motorised valves would allow better control than what you have just now.