I had two engineers round for this fault. One thought it was the switch (not the membrane), the other thought it was the membrane but said they can't buy just that, they need to change the whole pump block for £291+VAT! Note that we have the 23KW boiler and this part below fitted just fine.
Part to buy:
From: partscenter.co.uk
Search for: "E01-217" (GC number, it must have a dash in middle)
Part no: 463465
Name: Biasi BI1011102 domestic hot water pressure switch membrane
Price: £13.08+VAT+Delivery (Feb 2012)
Improved instructions for newbie's like me:
Fold the control unit down on left.
To remove the diaphragm, turn off cold water to boiler. You can turn off the main supply tap or the second tap in from the right under the boiler.
There are two differential tubes going into the top of the valve where the diaphragm is on the left side of the boiler, near the back (see photos on page 1).
Remove both clips holding these tubes in and remove with pliers and note the orientation of the clips – they fit into a slot.
There are two screws holding the valve in place. Unwind these a bit and the brass valve will come out.
Now undo the 6 screws, note which way the diaphragm is sat and replace with new one.
Put back together in reverse, replace the two o-rings if you can. Although, I found it easier to put the two differential tubes back in with the clips first, before refastening the valve.