Yes I was thinking about 100L would probably be about right.
I would suggest a 120L cylinder, to allow some small amount of spare capacity. The 10 minutes to recharge your 100L, sounds rather optimistic to me, and 24Kw unecessarily large for a flat - depending on the flats size....
I have a 3 bed semi, 120L open vented, and an modern 18Kw, condensing and modulating boiler, plus a fancy control scheme, in charge of it. It does the heating, or HW, but not both at the same time. It manages to reheat an entire cyclinder, in 25 - 30 minutes, but continues to cycle heating the HW until maybe 40 minutes. Even 18Kw, seems too big for our needs, able to quickly bring the house up to temperature within an hour, even in sub-zero temperatures outdoors. It then quickly modulates down, to minimum output.
The overnight setback temperature is 14C, the day setting is 18C, which begins at 10am. It took it just 20 minutes this morning, to get the 14C up to 18C.
You should be looking for a boiler, which has a good modulation range, the bigger the range, the more efficiently it can work, at low demands, and ensure the maximum Kw, is suitably rated for your property. Too large, and you will pay for it in lower economy.
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