No point with copper. Heat to cherry red and let cool it will be soft, annealed, copper hardens with age, working, planishing etc. When this has been done the joint must be scrupulously clean if soft soldered. Brazing, silver soldering etc are not so demanding hence less failure rate.
The other problem with making sockets is the operative will pull in one go stretching the bits in between the segments of the head making for a weak section. The way over this operative fault is to rotate the head in the forming socket thus revealing stress between the pulled sections. If you want to see this try making a socket in hard copper and see what I mean.
LeeC, don't get me wrong in the correct hands this tool can be a job £££££ saver especially new commercial, semi commercial, I have had a set since they were brought from the continent and supplied with the pucker riveted heads not the spring held in ones that diys seem to have bought on cost. I sometimes use it in retrofit situations however in domestic situations it not really cost effective (time v fitting) so not used often. Mine was mainly used in large hotels and supermarkets.
Tees: A lot of faf really, unless commercial as previously mentioned. When working in Belgium (prefab shop) the tees made were saddle tees and brazed, look inside boiler with copper, brass tubing and you will see what I mean.
Indeed there could be a case if pre-made couplers, tees and bends were not available at all , then the trades person would be back in demand as the skill level would be greater, but not the case.
Don't even think about placky pipe and push-fit fittings.