Aaahhh - so the overheat cut out could kick in because of low flow pressure (or something along those lines)??? To test this, today I left all radiator thermostats on full and controlled room temperature by turning down the heat on the boiler instead.
Now we have something to go on heres my latest thoughts on the matter
Overheat stat cuts in because the water it is sensing is above the 'cut out' temperature.
You need to look into possible reasons why the water might be getting too hot.
Poor flow through the boiler is one reason and can be caused several things.
If theres a setting available on the pump this should be at Max [3]
Are the valves fully open underneath?
Is there a bypass fitted? There should be and it should be set to 3 if its a honeywell one, otherwise just enough for the pump to force it open should all the TRVs close off the rest of the circuit.
Did you get more TRVs fitted with your new boiler to conform to the Chess specification that came in during 2005 ?
Have the max and min pressures been set up on the gas valve as it says in the MI's? Too much gas can boil your water up before your system can circulate it.
Its the CH thermistor that controls the heat of the water in your boiler and although they usually fail on the safe side. Yours being a new boiler will be the clip on type and it could be that it has slipped off the thermal paste and is giving a delayed reading. Sometimes too much thermal paste can cause a problem according to one of my discussions with Ravenheat who say all that is required is a thin smear.
Running your boiler on a lower setting would compensate for this and could be a simple solution. It would also rule out the rare possibilty that your new and old overheat stats are oversensitive, perhaps from a faulty batch.