What may be happening is that the resistance to flow of the water going down into the HWC from the CW cistern is more than enough to lower the water level in the vent pipe to the point where air starts to get into the cylinder, and through the flange, to the pump. It takes a few minutes to do it, typically. As a purely temporary measure, if you put eg a speedfit cap on the vent pipe you'll be able to prove it. Under no circumstances leave it there.
An anti-gravity loop is for what it says, to stop circulation by gravity (convection) which could lead to bubbles of air getting into the pipe, but these soon go through the pump, and don't form after a few minutes.
Problems due to the water being too hot start immediately the pump warms up - the hottest water is at the top of the cylinder.