Hive can have up to 6 zones (plus 1x HW, when needed) in a dwelling I read...
https://community.hivehome.com/s/ar...-Heating-if-I-have-a-Multizone-heating-system
As I read things you have 2 zones CH and UFH with 5 zones so Hive
should work for you with an additional 4 Hives and a bit of rewiring (making the current UFH hive control a UFH zone input and the UFH wiring centre control the zone valve, pump and boiler).
Alternatively you'd likely replace the UFH wiring control with a wireless version and the Salus wireless room stats connecting to it.
https://saluscontrols.com/gb/product/kl08rf-wireless-wiring-centre-for-8-zone/ No doubt quite expensive to do, as it is with the Drayton Wiser and Honeywell Evohome equivalent systems?