Thanks, i will be trying your suggestions. Just as i was typing this, sitting on the loo (tmi) i tried turning on the loo rad and suddenly it chose to work.
Maybe I'm just using the whole system incorrectly.
Will get photos of as much wiring as i can.
I think my biggest issue is understanding the relationship between the room stats and the trvs.
I have 2 room stats. 1 in zone 1 upstairs and 1 in zone 2 downstairs.
I then only have 1 rad in each room which now all have trvs.
I'm never sure if i need to turn on stats as well as trv or if i can just control trv and leave stat down.
Also i know you obviously bleed rads, so cylinders need bleeding as well as when i refilled the other day it hissed air which I've never heard before?
Sorry lots of questions!