... at a particular time of day, yes. However, as I said, although I haven't yet had a chance to investigate the theory, I suspect that things might gradually move (a little!) in the direction of that extreme as one moves away from a situation in which the total of loads is essentially the same throughout the 24 hours of the day - such that the 'energy loss benefit' of increasing voltage over a whole day might be less than your calculations would suggest.As you say, an extreme situation - and in practice won't happen. In part, that's why I suggested a large number of loads. Most large domestic loads are a) controlled and b) not in any way synchronised. So while the network load will not be constant, I expect it'll follow a fairly narrow spread centered around the average.
Is not the whole idea of 'smart demand management' to attempt to even out demand over the 24 hours of a day? If so, per the above, it would/will probably move us closer to the 'ideal' situation as regards the effect of voltage changes on energy loss?BUT, I suspect things may start changing with the pressure to move to smart demand management. So potential for large amounts of loads all turning on when a cheap charging period starts.