ok, so from my understanding... ( and rather simplified )
the MAIN EARTH has to be calculated via the adiabatic, but as a general rule of thumb must be...
same size as live if the live CSA is less than 16mm²
16mm² if live CSA is between 16mm² and 35mm²
half the size of the live for a live CSA bigger than 35mm²
============================
PEB's
MPB ( not the same as main earth.. these are bonds to water, gas, structural steel etc )
non PME supplies must be between 6mm² and 25mm² ( providing it's copper ) and not less than half the size of the main earth.. so a not less than a quarter of the size of the live.. ( given a typical supply with 25mm² tails, this works out to 6.25mm² minimum, so 10mm² is needed )
PME supplies, must comply with table 54.8 ( ie 10mm² for typical 25mm² tails.. )
suplimentary bonds minimum 2.5mm² if mechanically protected, 4mm² if not..
now the minimum sizes stated in table 54.1 are for buried conductors.. so as long as they comlpy with the above, you can have a 2.5mm² copper, mechanically protected conductor burried ( for example to an earth rod )
this does however mean that the supply tails would also have to be 2.5mm²...
the MAIN EARTH is not a protective bonding conductor, it is a circuit conductor and must conform to the rules set out for such ( as listed above )