Wrong way - testing (and any required repairs) first, replacement CU afterwards.
Before that, as an absolute minimum the old VOELCB should be removed and a 100mA RCD installed in it's place. That isn't technically compliant but will ensure that power is disconnected in the event of a fault.
Testing was done last year and the only item picked on it was the fact that no RCD protection was provided on the Ring main and lighting circuits. The rest were tested ok. And since the sockets were plastic, this was forgotten about. The only place with metal equipment, Fridge/Dishwasher/Wasing Machine/Kettle and ... was the kitchen which had RCBO fitted.
Testing this year: Still waiting for the EICR from the leccy but won't be holding my breath as he said it was a failure due to incorrect size of the earth spike cable! Needed 10mm even though it is not buried and protected! Gonna wait and see if he sends me his report and then if thats the only item on it, politely send him a note to refer him to OSG for the size of the conductor.
The only 100mA RCDs I can see are designed for DIN rail mounting. As the contacts won't be covered by protection, it will be a safety issue to have that fitted outside the CU. Do you have any links to ones that can be installed outside the CU? Unless I get a single Unit enclosure and mount it inside it?