Hi Doitall, i dont know what MV stands for.
Mike how do i find the diverter valve
Upgrademe, i'm going to check now
A diverter valve is a 3 way valve in your installation, usually sited near the hot water cylinder, hot water from the boiler is pumped into the middle port,
then the motorsied valve diverts it to either CH or HW ports or Both in the case of a 3 way valve, so it has 1 inlet and 2 outlets, one outlet feeds the Hot water cylinder Heating coil, the other port leads the hot water from the boiler to CH circuit.
But when you require both CH & HW, this diverter valve can hang midway and supply to both circuits.
Since you are getting some heating in your rads when you put your system in both modes, i.e. CH & HW, it then happily heats your CH radiators, but not quite, as you said they don't heat up well.
I didn't think they would heat up well, simply because, you have some partial restriction, which when you are in CH mode only does not allow sufficient flow through your CH circuit so overheats the boiler which cuts out, but in dual mode (CH+HW) it does not cut out and heats up the rads as some flow even though much restricted does flow through the rads or the CH circuit.
in HW mode, there appears to be no blockages or restrictions, so it flows happily, and the boiler does not shut down due to overheat. But I am not sure if it would shut down when your hot water thermostate has reached the desired temeprature, then the diverter valev would change and divert all the hot water from the boiler to CH, in which case your boiler would shut down due to flow restriction, when it is in both CH+HW mode, again depending on the thermostate settings in room and on the cylinder.
So in my view your problkem appwears to be associated very close to this 3 way valve, on the port that feeds CH flow, but not return,however, there can be a problem in the return too, I am not ruling that out. But I would check this 3 way valve ports and the CH circuits are all clear of any obstruction, have all your rad valves fully open.