I poked out a Proster Thermocouple Thermometer (never used) that somebody gave me a present of 3 or 4 years ago and heated up a pot of water. My probes are also stamped K type but you can select 4 or 5 different settings, I compared the K reading with types E & T, type E read consistently lower than K and T,Yeah I'll do this tomorrow. I tried it with just the non-TRV rads on and the dial set even lower, still went up to 65C or something. It's definitely not working properly - either that or my thermometer. If I select type E thermocouples on my thermometer instead of type K the numbers look right But they are definitely stamped as type K.
It was 11 last night and 16 during the day here, and my room is now 19C inside. The forecast for the next week is for highs of 16-18C and lows of 13-14C.
At a measured (with a rototherm ) "55C", K:54.4C. T:54.0. E:43.6C.
Pot boiling so had to be at 100C. K:99.7C. T:98.3C. E:72.8C
Based on that the K scale is the correct one to use so your K readings are also correct and not Es??.